Department of Energy Argonne National Laboratory Office of Science NEWTON's Homepage NEWTON's Homepage
NEWTON, Ask A Scientist!
NEWTON Home Page NEWTON Teachers Visit Our Archives Ask A Question How To Ask A Question Question of the Week Our Expert Scientists Volunteer at NEWTON! Frequently Asked Questions Referencing NEWTON About NEWTON About Ask A Scientist Education At Argonne Dye and Pigment Differences
Name:  David M.
Status: other
Age: 50s
Location: N/A
Country: N/A
Date: 11/27/2004


Question:
What is the difference between a dye and a pigment?


Replies:
Dyes are dissolved in whatever solvent is used. Pigments are insoluble. Often a pigment is made by attaching a dye molecule to an insoluble particle.

Vince Calder


Hi David,

According to my sources a pigment is a coloring matter, usually in the form of an insoluble powder that is mixed with oil, water, etc. to make paint. The pigment lays on the surface and becomes part of the dry film.

A dye is soluble in water and is used to color cloth, basket reed and other porous materials.

Hope this helps,

Martha Croll


Definitions are not well established, but mine is:

A dye is a molecule or chemical which absorbs light more at some visible wavelengths than at others. Added to a clear medium, it gives clear colors. Transparent, not even milky or translucent. Added to an opaque medium such as concrete, the opacity remains, some color is added, and the net gray-equivalent brightness is always reduced, because a dye can only absorb light.

A pigment is a mixture of dye and an opacifying agent, such as white oxide powders which scatter light or dark colored powders which both absorb and scatter. So the colors they add are opaque; i.e. it looks more like paint, regardless of whether the original medium was clear or opaque. A white or light-colored pigment can sometimes make a dark medium lighter, provided the original medium was more translucent than the pigment.

This translucency can be quantified. Virtually every opaque material becomes transparent or translucent if sliced thin enough. For light-scattering materials, the thickness which deflects 63% of the light can be called the "scattering length". In effect, this is about the minimum thickness which would fuzz-up your view and stop you from reading a newspaper through it, if held a certain distance above the paper. Adding enough white or silver or black powder to a medium shortens the scattering length. This enables light-colored pigments to seize control of the color of medium-gray concrete and make it white or light colors. A pure dye could never do that, could only make the gray into dark or perhaps medium colors.

Textiles already have plenty of scattering for their uses, so to color them all you need is dye. Adding powder would not endure anyway; it would soon wash out, causing the color you added to change.

In the field of resins for fiberglass lamination or casting, the words are used interchangeably, even though some color additives are clear and others have opacifying agents in them. I find this unfortunate.

The freeware 3-D photo-realistic rendering software "POV-Ray" uses the word "pigment" to label a collection of color properties which can be applied to a surface. I don't yet understand exactly which properties they allow their term to include, but it's probably more complex than just colored absorption, and results in some opacity. I find learning to use POV-Ray "visually educating".

Many dye additives, as delivered, are so concentrated and absorbing that they have a color-tinged black appearance. but if you spread one drop thinly over a surface you could read fine print through it. Food coloring is a water-soluble example of what I would call dye.

A tube of white toothpaste would be a white pigment for some imaginary use. The same toothpaste, with a red dye added, would be a pink or red pigment. With an overwhelming concentration of dyes, or with black powder added, it could be a black pigment. Silver or metallic colorants can only be pigment.

"Stain" tends to mean a dye with selective uptake: some parts of the stained object get darker than others by retaining more of the colorant. Wood stains intensify the visibility of the wood's grain; biological stains selectively color certain substances for viewing in the microscope.

Hope that adds something relevant to your field.

Jim Swenson



Click here to return to the General Topics Archives

NEWTON is an electronic community for Science, Math, and Computer Science K-12 Educators, sponsored and operated by Argonne National Laboratory's Educational Programs, Andrew Skipor, Ph.D., Head of Educational Programs.

For assistance with NEWTON contact a System Operator (help@newton.dep.anl.gov), or at Argonne's Educational Programs

NEWTON AND ASK A SCIENTIST
Educational Programs
Building 360
9700 S. Cass Ave.
Argonne, Illinois
60439-4845, USA
Update: June 2012
Weclome To Newton

Argonne National Laboratory