Department of Energy Argonne National Laboratory Office of Science NEWTON's Homepage NEWTON's Homepage
NEWTON, Ask A Scientist!
NEWTON Home Page NEWTON Teachers Visit Our Archives Ask A Question How To Ask A Question Question of the Week Our Expert Scientists Volunteer at NEWTON! Frequently Asked Questions Referencing NEWTON About NEWTON About Ask A Scientist Education At Argonne Metallic Property Changes Upon Heating and Cooling
Name:Randy
Status: educator
Grade: 9-12
Location: WI
Country: USA
Date: September 2007


Question:
After heating a pure copper penny in a Bunsen burner flame until it glows orange and then cooling the penny off, its appearance does not change (except that it looks newer). However, when the penny is dropped from high up or thrown down on a lab table, it does not bounce. Comparing it to a normal copper penny shows a dramatic difference. Why is that?



Replies:
Randy,

There are two reasons I can think of that could give this result: (1) the macro crystal structures of the penny has annealed and made a harder denser structure, or (2) the filler material in the (modern) penny has deteriorated and is now more mobile.

In the first case, the crystal macrostructures of metals can be changed by a process called annealing. It is not so much that the crystal structure - the way the atoms are put together that changes, but rather, the way the individual crystal comes together to form larger, macrostructures. The whole coin is not one complete and uniform crystal of the metal alloys. Rather it is made up of small crystals that organize themselves into bigger structures. As such, between these crystal structures are grain boundaries, errors in the way the crystals came together, or crystal structures that may slip across the face of other crystals. Heating the coin may cure some of these imperfections and make bigger, more uniformly joined crystals. This also means that the coin becomes harder and possibly less elastic.

On the other hand, the heat can change the metal structures in the alloys and make them more able to disperse the energy as heat - making the collision less elastic. This can happen in modern coins that have cheaper alloys that do not retain their crystal structures when heated. Heating can then cause higher mobility of the atoms or crystals which means that the kinetic energy absorbed during collision is dispersed through the coin as heat (movement of particles). This energy is lost and not returned as an elastic collision.

Try to see if there is a difference between how much energy it takes to bend the penny. If the penny is harder to bend, then annealing has taken place and the more uniform crystal macrostructures are the reason for the poorer bounce. If the penny is easier to bend, then the weaker bounce is a result of better energy dispersion through the coin.

Greg (Roberto Gregorius)


The color is merely a surface condition. The inside of the flame has more H and C from fuel than O from air, so it is a reducing environment and will change copper oxide back to copper. The surface color goes from dark-tarnished to bright& copper-colored.

Bouncing depends on the mechanical properties of the bulk of the metal, such as elasticity and stiffness and strength. When greatly heated the crystallization state of the metal will change.

Probably the metal of you penny was cold-worked to a "hardened" state when it was coin-stamped, long before you got it.

Cold-working means when a metal is forcibly deformed, the flow trips up internally and makes defects, which then tend to act as sticking points that reduce further flow. So thereafter the metal flexes and recovers in a spring-like fashion, and is harder to permanently bend or dent.

Then when you heated it the penny the metal was annealed. All those defects, that made the metal act hard and ringing and bouncing, were healed as metal atoms moved around, freed by the high temperature. Now the metal is softer, easier to bend and possibly duller in ringing sound. So when a force is applied by impact on the table, the deformation is permanent bending instead of temporary lossless flexing. The penny will not bounce as high because energy was absorbed by that bending.

Complications:

Recent pennies are zinc alloy with copper cladding. If you heated the penny hot enough the zinc and copper may have mixed a little. zinc+ copper = brass, which tends to be a little lighter-colored than copper. Maybe this was partly responsible for the brightening you saw. And the zinc alloy is probably the bulk metal which was annealed. Mixing of copper into the zinc could have had some effect on mechanical properties too. Heating "red hot" must have nearly melted the zinc inside...

Jim Swenson



Click here to return to the Chemistry Archives

NEWTON is an electronic community for Science, Math, and Computer Science K-12 Educators, sponsored and operated by Argonne National Laboratory's Educational Programs, Andrew Skipor, Ph.D., Head of Educational Programs.

For assistance with NEWTON contact a System Operator (help@newton.dep.anl.gov), or at Argonne's Educational Programs

NEWTON AND ASK A SCIENTIST
Educational Programs
Building 360
9700 S. Cass Ave.
Argonne, Illinois
60439-4845, USA
Update: June 2012
Weclome To Newton

Argonne National Laboratory