Question:
Is Aluminum chloride a molecular compound or an ionic
compound? Does it have a trigonal planar geometry like Boron trichloride
or is it just ionic?
Replies:
In the solid phase aluminum chloride is an ionic compound; however, in the
vapor phase it is a dimer Al2Cl6 in which the two aluminum atoms are
bridged by two Cl atoms. Like many metal salts the molecular structure
depends upon the physical state of the substance.
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