Question:
Why does Aluminum react with cupric chloride, but does not react
with copper sulfate or NaCl, but does yield a reaction when you add Aluminum
into a mixture of copper sulfate+NaCl?
Replies:
Of course, as you realize copper sulfate + NaCl is also a form of cupric chloride
with some sodium sulfate thrown in. I suspect that the underlying reason is the
pH of the solutions. The HSO4(-1) the dominant anion present in solution may be
buffering the solution, but that is only a guess, in the absence of doing the
experiment.
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