Department of Energy Argonne National Laboratory Office of Science NEWTON's Homepage NEWTON's Homepage
NEWTON, Ask A Scientist!
NEWTON Home Page NEWTON Teachers Visit Our Archives Ask A Question How To Ask A Question Question of the Week Our Expert Scientists Volunteer at NEWTON! Frequently Asked Questions Referencing NEWTON About NEWTON About Ask A Scientist Education At Argonne Heating Plastics
Name: John A.
Status: educator
Age: 40s
Location: N/A
Country: N/A
Date: 2001 - 2002


Question:
I am interested in knowing what is the best procedure to melt recycled plastic and mixing it with fine recycled rubber crumb. have given 10 students the task to manufacture a rubber mat using these recycled products.

I want to use the recycled plastic as the binding agent mixed in with the rubber crumb.

I believe that some recycled plastic is not conducive to melting , so I would appreciate some information to what types of plastic recycled material would best suit this process.


Replies:
Your inquiry raises a number of questions in addition to the one you asked explicitly. There are two general types of plastics: thermosetting and thermoplastic. The former will not melt when heated, just decompose and/or oxidize; the latter will soften when heated. Rubber, Bakelite, urea-formaldehyde copolymers are examples of thermosetting polymers; methyl methacrylate (Plexiglas), polystyrene, polyethylene are examples of thermoplastic polymers. Some acrylate, styrene, and polyethylene polymers can be found in both thermoplastic and thermosetting forms. You will need to use thermoplastic recycle.

When the thermoplastic polymer is heated, say in the range of 100-300 C. the melt will be VERY viscous. You will require some heavy duty blending equipment such as "dough" mixers, "roller" mills, or extruders. Otherwise it will not be possible to obtain a uniform blend of binder polymer and rubber crumb. In addition, these types of equipment are potentially very dangerous, and should not be used by untrained personnel. Close supervision is a must. You will need the elevated temperature also in order to "wet" the rubber crumb with the binding polymer. Hot polymer melts are also VERY hazardous because if they come into contact with skin, they cannot be wiped or brushed off. They will cause serious deep burns.

The mixing process will have to be done with ventilating exhaust because some of the polymers will de-polymerize (polystyrene and methyl methacrylate for example) and/or contain volatile components that you cannot allow to be released into the facility for safety reasons.

The crumb/binder ratio will have to be determined, if it has not been done previously, because this will have a large effect on both the melt viscosity and properties of the final product.

If the "mix" is made successfully, how will the mats be fabricated? What are the wear properties of the mats -- both interior and exterior? That is, will the mats leave black marks on light linoleum? Will the mats withstand the abrasion of wiping sand and/or mud? Will the mats weather well -- that is, withstand freeze/thaw cycling, water immersion, exposure to sunlight?

Yours is a pretty complex project that will require careful planning and execution.

Vince Calder



Click here to return to the Chemistry Archives

NEWTON is an electronic community for Science, Math, and Computer Science K-12 Educators, sponsored and operated by Argonne National Laboratory's Educational Programs, Andrew Skipor, Ph.D., Head of Educational Programs.

For assistance with NEWTON contact a System Operator (help@newton.dep.anl.gov), or at Argonne's Educational Programs

NEWTON AND ASK A SCIENTIST
Educational Programs
Building 360
9700 S. Cass Ave.
Argonne, Illinois
60439-4845, USA
Update: February 2012
Weclome To Newton

Argonne National Laboratory